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Glutathione exists primarily in two interrelated forms: Reduced glutathione, or GSH: the form able to donate electrons within antioxidant and redox reactions Oxidized glutathione, or GSSG: the form produced after two glutathione molecules form a disulfide bond The body continually recycles oxidized glutathione back into reduced glutathione through enzyme systems that depend partly on cellular energy and nutrient availability

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1 2 "Three-dimensional structure of a mammalian thioredoxin reductase: implications for mechanism and evolution of a selenocysteine-dependent enzyme"