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Another is the intestinal-renal axis for arginine: the small intestine is a net producer of citrulline from glutamine and other precursors, especially after meals or during stress [77]

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In summary, within both the inherent supramolecular assemblies of classic TCM decoctions and engineered metal-natural product nanomedicine systems, trace metal ion coordination serves as a pivotal driver of supramolecular self-assembly and structural/functional optimization